Coordination-Induced Formation of One-Dimensional Nanostructures of Europium Benzene-1,3,5-tricarboxylate and Its Solid-State Thermal Transformation

被引：89

作者：

Liu, Kai ^{[1
,2
]}

You, Hongpeng ^{[1
]}

Jia, Guang ^{[1
,2
]}

Zheng, Yuhua ^{[1
,2
]}

Song, Yanhua ^{[1
,2
]}

Yang, Mei ^{[1
,2
]}

Huang, Yeju ^{[1
,2
]}

Zhang, Hongjie ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 08期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; HYBRID MATERIALS; GROWTH; NANOCRYSTALS; COMPLEXES; PHOTOLUMINESCENCE; NANOWIRES; NANOTUBES; NANOBELTS; NANORODS;

D O I：

10.1021/cg900252r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel one-dimensional europium benzene-1,3,5-tricarboxylate compressed nanorods have been synthesized oil it large scale through direct precipitation in solution phase under moderate conditions without the assistance of any surfactant, catalyst, or template. The obtained nanorods have widths of about 50-100 not, thicknesses of 10-20 nm, and lengths ranging from a few hundred nanometers to several micrometers. X-ray powder diffraction. elemental analysis, Fourier transform infrared Studies, and thermogravimetric and differential thermal analysis show that the nanorods have the structural formula of Eu(1,3,5-BTC)center dot 6H(2)O. Upon UV excitation, these nanorods exhibit a highly efficient luminescence. which comes from the Eu3+ ions. Moreover, Eu2O3 nanorods Could also be obtained via a thermal decomposition method using the corresponding complex as a precursor. This synthetic route is promising for the preparation of other one-dimensional crystalline nanomaterials because of its simplicity and the low cost of the starting reagents.

引用

页码：3519 / 3524

页数：6

共 54 条

[41] Ternary nets formed by self-assembly of triangles, squares, and tetrahedra [J].