Gold and Palladium Combined for Cross-Coupling

被引：174

作者：

Hashmi, A. Stephen K. ^{[1
]}

Lothschuetz, Christian ^{[1
]}

Doepp, Rene ^{[1
]}

Rudolph, Matthias ^{[1
]}

Ramamurthi, Tanuja D. ^{[1
]}

Rominger, Frank ^{[1
]}

机构：

[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 44期

关键词：

carbene ligands; cross-coupling; gold; palladium; transmetalation; HETEROCYCLIC CARBENE COMPLEXES; STRUCTURAL-CHARACTERIZATION; SUZUKI-MIYAURA; CARBON CHAINS; BOND FORMATION; ARYL; CATALYSIS; TRANSMETALATION; CYCLIZATION; EFFICIENT;

D O I：

10.1002/anie.200902942

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Gold and palladium-a unique liason: A study of the transmetalation abilities of organogold compounds builds the basis for a new class of cross-coupling reactions. Stable intermediates of gold catalysis deliver new complex products by a palladium-catalyzed coupling reaction, (see Scheme) © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8243 / 8246

页数：4

共 42 条

[1]

[Anonymous], 2007, ANGEW CHEM-GER EDIT

[2]

A novel methodology for the synthesis of complexes containing long carbon chains linking metal centres:: molecular structures of {Ru(dppe)Cp*}2(μ-C14) and {Co3(μ-dppm)(CO)7}2(μ3:μ3-C16) [J].

Antonova, AB ;

Bruce, MI ;

Elis, BG ;

Gaudio, M ;

Humphrey, PA ;

Jevric, M ;

Melino, G ;

Nicholson, BK ;

Perkins, GJ ;

Skelton, BW ;

Stapleton, B ;

White, AH ;

Zaitseva, NN .

CHEMICAL COMMUNICATIONS, 2004, (08) :960-961

[3]

Alternative synthetic methods through new developments in catalysis by gold [J].

Arcadi, Antonio .

CHEMICAL REVIEWS, 2008, 108 (08) :3266-3325

[4]

A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides [J].

Biscoe, Mark R. ;

Fors, Brett P. ;

Buchwald, Stephen L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (21) :6686-+

[5]

Construction of carbon chains on ruthenium and osmium carbonyl clusters [J].

Bruce, MI ;

Humphrey, PA ;

Melino, G ;

Skelton, BW ;

White, AH ;

Zaitseva, NN .

INORGANICA CHIMICA ACTA, 2005, 358 (05) :1453-1468

[6]

A new approach to the synthesis of carbon chains capped by metal clusters [J].

Bruce, MI ;

Smith, ME ;

Zaitseva, NN ;

Skelton, BW ;

White, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 670 (1-2) :170-177

[7]

Luminescent molecular copper(I) alkynyl open cubes: Synthesis, structural characterization, electronic structure, photophysics, and photochemistry [J].

Chan, Chui-Ling ;

Cheung, Kai-Leung ;

Lam, Wai Han ;

Cheng, Eddie Chung-Chin ;

Zhu, Nianyong ;

Choi, Sam Wing-Kin ;

Yam, Vivian Wing-Wah .

CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (1-2) :273-286

[8]

A bis(ortho-amine)aryl-gold(I) compound as an efficient, nontoxic, arylating reagent [J].

Contel, M ;

Stol, M ;

Casado, MA ;

van Klink, GPM ;

Ellis, DD ;

Spek, AL ;

van Koten, G .

ORGANOMETALLICS, 2002, 21 (21) :4556-4559

[9]

New heterogenized gold(I)-heterocyclic carbene complexes as reusable catalysts in hydrogenation and cross-coupling reactions [J].

Corma, A. ;

Gutierrez-Puebla, E. ;

Iglesias, M. ;

Monge, A. ;

Perez-Ferreras, S. ;

Sanchez, F. .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (14) :1899-1907

[10]

PREPARATION AND LIGAND-EXCHANGE REACTIONS OF PHOSPHINEGOLD ETHYNYL COMPLEXES [J].

CROSS, RJ ;

DAVIDSON, MF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (02) :411-414

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