Synthesis and characterization of the platinum complexes with N,S or C,N,S ligands derived from 2-phenylbenzothiazoline

被引：23

作者：

Kawamoto, T

Nagasawa, I

Kuma, H

Kushi, Y

机构：

来源：

INORGANICA CHIMICA ACTA | 1997年 / 265卷 / 1-2期

关键词：

crystal structures; platinum complexes; N; S-ligand complexes; C;

D O I：

10.1016/S0020-1693(97)05641-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of the two platinum complexes, the thiolato-bridged tetranuclear [Pt-4 (phbt)(4)] and the neutral dithiolene-like non-innocent mononuclear [Pt(ddbt)], is described. [Pt-4(phbt)(4)]. 2CH(2)ClCH(2)Cl crystallizes in the monoclinic space group P2(1)/n, with a = 19.893(5), b = 17.950(7), c = 14.844(4) Angstrom, beta = 93.69(2)degrees, V = 5289(3) Angstrom(3) and Z = 4. [Pt(ddbt)] crystallizes in the monoclinic space group P2(1)/n,with a = 10.789(9), b = 24.56(2), c = 8.64(1) Angstrom, beta = 102.69(8)degrees, V = 2232(4) Angstrom(3) and Z = 4. (C) 1997 Elsevier Science S.A.

引用

页码：163 / 167

页数：5

共 13 条

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