Hydroxyl radical scavenging and producing activities of water-soluble malonic acid C60

被引:3
作者
Cheng, FY [1 ]
Yang, XL [1 ]
Zhu, HS [1 ]
机构
[1] Beijing Inst Technol, Res Ctr Mat Sci, Beijing 100081, Peoples R China
来源
FULLERENE SCIENCE AND TECHNOLOGY | 2000年 / 8卷 / 1-2期
基金
中国国家自然科学基金;
关键词
D O I
10.1080/10641220009351402
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of several water-soluble malonic acid derivatives of C-60 with different addition number (M1 similar to M4) on hydroxyl radical were studied by ESR method. It was shown that the OH signal produced by the Fenton system could be remarkably reduced by M1 and M2, but could not by M3 and M4. The action of M1 and M2 was dose-dependent, and M1 was found to be more effective than M2. In addition, under irradiation and in the presence of oxygen, M2 could produce hydroxyl radicals. These data indicate that the quenching activity of the malonic acid derivative of C-60 was closely related to the integrity of conjugated double bonds, and some C-60 derivatives with specific structures might act as the eliminator or producer of hydroxyl radicals under different conditions.
引用
收藏
页码:113 / 124
页数:12
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