Thermal activation of methane by tetranuclear [V4O10]+

被引：218

作者：

Feyel, Sandra

Doebler, Jens

Schroeder, Detlef

Sauer, Joachim

Schwarz, Helmut

机构：

[1] Humboldt Univ, Inst Chem, D-10099 Berlin, Germany

[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 28期

关键词：

C-H activation; density functional calculation; mass spectrometry; molecular dynamics; vanadium oxides;

D O I：

10.1002/anie.200600188

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Hand in hand: In a combination of experimental (mass spectrometry) and theoretical (density functional theory) studies [V 4O10]+ is described as the first polynuclear transition-metal oxide capable of activating methane at room temperature (see picture). The [V4O10]+ cation can be considered a prototype of oxide clusters of early 3d transition metals. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：4681 / 4685

页数：5

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