Diastereoselective photochemical synthesis of 3,3'-disubstituted indolines

被引：12

作者：

IbrahimOuali, M

Sinibaldi, ME

Troin, Y

Guillaume, D

Gramain, JC

机构：

[1] SEESIB,UMR 6504,F-63177 AUBIERE,FRANCE

[2] ENSCCF,LAB CHIM HETEROCYCLES & GLUCIDES,F-63174 AUBIERE,FRANCE

[3] UNIV PARIS 05,FAC SCI PHARMACEUT & BIOL,CNRS,URA 1310,F-75270 PARIS 06,FRANCE

来源：

TETRAHEDRON | 1997年 / 53卷 / 47期

关键词：

D O I：

10.1016/S0040-4020(97)10028-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Spiroindoline lactams 9 and imides 11 were efficiently and diastereoselectively prepared by photocyclization of N-arylenaminolactams 8 and esters 5 respectively. Imides 11 were conveniently transformed into the known indolines 13 and 14 which are key intermediates for the synthesis of (+/-)-vindorosine and Aspidosperma alkaloids. (C) 1997 Elsevier Science Ltd.

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页码：16083 / 16096

页数：14

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