Palladium-bipyridine catalyzed conjugate addition of arylboronic acids to α,β-unsaturated carbonyl compounds in aqueous media

被引：40

作者：

Lin, Shaohui ^{[1
]}

Lu, Xiyan ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 40期

基金：

中国国家自然科学基金;

关键词：

palladium; arylboronic acids; alpha; beta-unsaturated carbonyl compounds; aqueous media; conjugate addition;

D O I：

10.1016/j.tetlet.2006.07.154

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium/bipyridine catalyzed conjugate addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds in aqueous media was developed with high yields. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：7167 / 7170

页数：4

共 15 条

[1]

Anastas P. T., 1998, GREEN CHEM FRONTIERS

[2]

Cornils B., 2006, Aqueous -Phase Organometallic Catalysis: Concepts and Applications

[3] Rhodium-catalyzed asymmetric 1,4-addition and its related asymmetric reactions [J].

Hayashi, T ;

Yamasaki, K .

CHEMICAL REVIEWS, 2003, 103 (08) :2829-2844

[4]

Krause N, 2001, SYNTHESIS-STUTTGART, P171

[5]

Li C. -J., 1997, ORGANIC REACTIONS AQ

[6] Organic reactions in aqueous media with a focus on carbon-carbon bond formations: A decade update [J].

Li, CJ .

CHEMICAL REVIEWS, 2005, 105 (08) :3095-3165

[7] Organic chemistry in water [J].

Li, CJ ;

Chen, L .

CHEMICAL SOCIETY REVIEWS, 2006, 35 (01) :68-82

[8] Pd(II)-bipyridine catalyzed conjugate addition of arylboronic acid to α,β-unsaturated carbonyl compounds [J].

Lu, XY ;

Lin, SH .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (23) :9651-9653

[9] Control of the β-hydride elimination making palladium-catalyzed coupling reactions more diversified [J].

Lu, XY .

TOPICS IN CATALYSIS, 2005, 35 (1-2) :73-86

[10] 1,4-addition of axylboronic acids and arylsiloxanes to α,β-unsaturated carbonyl compounds via transmetalation to dicationic palladium(II) complexes [J].

Nishikata, T ;

Yamamoto, Y ;

Miyaura, N .

ORGANOMETALLICS, 2004, 23 (18) :4317-4324

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