Synthesis and properties of functional tetrasilanes and hexasilanes

被引：14

作者：

Baumeister, U

Schenzel, K

Zink, R

Hassler, K

机构：

[1] GRAZ TECH UNIV,INST ANORGAN CHEM,A-8010 GRAZ,AUSTRIA

[2] UNIV HALLE WITTENBERG,INST PHYS CHEM,D-06108 HALLE,GERMANY

[3] UNIV HALLE WITTENBERG,INST ANALYT CHEM & UMWELTCHEM,D-06120 HALLE,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 543卷 / 1-2期

关键词：

D O I：

10.1016/S0022-328X(97)00127-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The methylphenylsilanes Ph2Si(SiMe3)(2), SiMe3SiPh2SiPh2SiMe3, SiMe3SiPh2SiPh2SiPh2SiMe3, PhSi(SiMe3)(3) and (SiMe3)(2)SiPhSiPh(SiMe3)(2) have been prepared by dehalogenation of mixtures of Ph2SiMe2/ClSiMe3 and PhSiCl3/ClSiMe3 with sodium-potassium alloy or by reductive coupling of appropriate triflated silanes with lithium. The reactions of the silanes with HX/AlX3 (X = Cl, Br, I) as well as triflic acid have been investigated and the crystal structure of the tetrasilane Me3SiSiPh2SiPh2SiMe3 has been determined.

引用

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页码：117 / 124

页数：8

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