Formation of polymer vesicles by simultaneous chain growth and self-assembly of amphiphilic block copolymers

被引:142
作者
Delaittre, Guillaume [1 ,2 ]
Dire, Charlotte [1 ,2 ]
Rieger, Jutta [1 ,2 ]
Putaux, Jean-Luc [3 ]
Charleux, Bernadette [1 ,2 ]
机构
[1] Univ Paris 06, Lab Chim Polymeres, F-75252 Paris 05, France
[2] CNRS, UMR 7610, F-75252 Paris 05, France
[3] Univ Grenoble 1, CERMAV CNRS, Ctr Rech Macromol Vegetales, F-38041 Grenoble 9, France
关键词
FREE-RADICAL POLYMERIZATION; DIBLOCK COPOLYMER; IN-SITU; NANOPARTICLES; NANOREACTORS;
D O I
10.1039/b903040a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymerization-induced formation of amphiphilic diblock copolymer vesicles is performed in water at high concentrations by a single-step nitroxide-mediated controlled free-radical emulsion polymerization of 4-vinylpyridine, initiated by a water-soluble poly(sodium acrylate) macroalkoxyamine at alkaline pH.
引用
收藏
页码:2887 / 2889
页数:3
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