Use of nuclear magnetic resonance imaging as a viscometer for process monitoring

被引:54
作者
Arola, DF
Barrall, GA
Powell, RL
McCarthy, KL
McCarthy, MJ
机构
[1] UNIV CALIF DAVIS,DEPT CHEM ENGN & MAT SCI,DAVIS,CA 95616
[2] QUANTUM MAGNET,SAN DIEGO,CA 92121
基金
美国国家科学基金会;
关键词
nuclear magnetic resonance imaging; viscometer; viscosity; shear rate; velocity;
D O I
10.1016/S0009-2509(97)00033-X
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Nuclear magnetic resonance imaging (NMRI or MRI) flow measurements and fundamental principles of capillary flow are combined to determine the shear viscosity of non-Newtonian fluids. Shear viscosity data are obtained over the shear rates inferred from the velocity profile measured using MRI. A single, 3 minute measurement consisting of a MRI-determined velocity profile (also referred to as a dynamic displacement profile or position-displacement correlation) and the corresponding pressure drop produces multiple shear viscosity-shear rate data points. This technique was applied to obtain shear viscosity-shear rate data for an aqueous carboxymethyl cellulose (CMC) solution. Good agreement is found between these data and those measured by conventional rotational rheometry. The potential applications of this MRI-based technique include on-line and in-line monitoring of the shear viscosity of single and multiphase non-Newtonian fluids that can be either opaque or transparent. (C) 1997 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2049 / 2057
页数:9
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