Use of nuclear magnetic resonance imaging as a viscometer for process monitoring

被引:54
作者
Arola, DF
Barrall, GA
Powell, RL
McCarthy, KL
McCarthy, MJ
机构
[1] UNIV CALIF DAVIS,DEPT CHEM ENGN & MAT SCI,DAVIS,CA 95616
[2] QUANTUM MAGNET,SAN DIEGO,CA 92121
基金
美国国家科学基金会;
关键词
nuclear magnetic resonance imaging; viscometer; viscosity; shear rate; velocity;
D O I
10.1016/S0009-2509(97)00033-X
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Nuclear magnetic resonance imaging (NMRI or MRI) flow measurements and fundamental principles of capillary flow are combined to determine the shear viscosity of non-Newtonian fluids. Shear viscosity data are obtained over the shear rates inferred from the velocity profile measured using MRI. A single, 3 minute measurement consisting of a MRI-determined velocity profile (also referred to as a dynamic displacement profile or position-displacement correlation) and the corresponding pressure drop produces multiple shear viscosity-shear rate data points. This technique was applied to obtain shear viscosity-shear rate data for an aqueous carboxymethyl cellulose (CMC) solution. Good agreement is found between these data and those measured by conventional rotational rheometry. The potential applications of this MRI-based technique include on-line and in-line monitoring of the shear viscosity of single and multiphase non-Newtonian fluids that can be either opaque or transparent. (C) 1997 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2049 / 2057
页数:9
相关论文
共 74 条
[31]   SIMULTANEOUS MEASUREMENT OF MASS AND VISCOSITY USING PIEZOELECTRIC QUARTZ CRYSTALS IN LIQUID-MEDIA [J].
HAYWARD, GL ;
CHU, GZ .
ANALYTICA CHIMICA ACTA, 1994, 288 (03) :179-185
[32]   PULSED FIELD-GRADIENT SPIN-ECHO NMR STUDIES OF FLOW IN FLUIDS [J].
HAYWARD, RJ ;
TOMLINSON, DJ ;
PACKER, KJ .
MOLECULAR PHYSICS, 1972, 23 (06) :1083-+
[33]   NMR SPINNING SIDE-BAND AND SPIN ECHOES - IMAGING OF COUETTE-FLOW [J].
HOPKINS, JA ;
GRUTZNER, JB .
JOURNAL OF MAGNETIC RESONANCE SERIES A, 1994, 111 (01) :17-22
[34]   MEASUREMENT OF SELF-DIFFUSION COEFFICIENT OF EACH COMPONENT IN A COMPLEX SYSTEM USING PULSED-GRADIENT FOURIER-TRANSFORM NMR [J].
JAMES, TL ;
MCDONALD, GG .
JOURNAL OF MAGNETIC RESONANCE, 1973, 11 (01) :58-61
[35]   THE MEASUREMENT OF VELOCITY PROFILES - AN APPLICATION OF NMR MICROSCOPY [J].
JEFFREY, KR ;
CALLAGHAN, PT ;
XIA, Y .
FOOD RESEARCH INTERNATIONAL, 1994, 27 (02) :199-201
[36]   NMR IMAGING STUDIES OF STRATIFIED FLOWS IN A HORIZONTAL ROTATING CYLINDER [J].
JEONG, EK ;
ALTOBELLI, SA ;
FUKUSHIMA, E .
PHYSICS OF FLUIDS, 1994, 6 (09) :2901-2906
[37]   THE PROPAGATOR REPRESENTATION OF MOLECULAR-TRANSPORT IN MICROPOROUS CRYSTALLITES [J].
KARGER, J ;
HEINK, W .
JOURNAL OF MAGNETIC RESONANCE, 1983, 51 (01) :1-7
[38]   A NOVEL X-RAY RHEOMETER FOR IN-SITU STUDIES OF POLYMER MELTS AND SOLUTIONS DURING SHEAR-FLOW [J].
KEATES, P ;
MITCHELL, GR ;
PEUVRELDISDIER, E ;
RITI, JB ;
NAVARD, P .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 1994, 52 (02) :197-215
[39]   SPATIAL-MAPPING OF VELOCITY POWER SPECTRA IN TAYLOR-COUETTE FLOW USING ULTRAFAST NMR IMAGING [J].
KOSE, K .
PHYSICAL REVIEW LETTERS, 1994, 72 (10) :1467-1470
[40]   NMR FLOW IMAGING [J].
KOSE, K ;
SATOH, K ;
INOUYE, T ;
YASUOKA, H .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1985, 54 (01) :81-92