Palladium-catalyzed asymmetric allylation and complex formation involving P,N-bidentate derivatives of (S)-2-(anilinomethyl)pyrrolidine

被引：10

作者：

Bondarev, OG

Gavrilov, KN

Tsarev, VN

Davankov, VA

Lebedev, RV

Moiseev, SK

Kalinin, VN

机构：

[1] SA Esenin Ryazan State Pedag Univ, Ryazan 390000, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 03期

关键词：

P; N-ligands; aminophosphites; palladiun; rhodium; asymmetric synthesis; allylation; carboranes;

D O I：

10.1023/A:1015576706429

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

P,N-Bidentate (S)-2-(anilinomethyl)pyrrolidine derivatives and their complexes with rhodium((I)) and palladium((II)) were synthesized. It was demonstrated that these compounds can be used in the Pd-catalyzed asymmetric allylation for the synthesis of chiral methyl 2-phenyl-2-(2-phenyl-o-carboranyl-1)pent-4-enoate.

引用

页码：521 / 525

页数：5

共 32 条

[1]

Alexakis A, 2000, EUR J ORG CHEM, V2000, P4011, DOI 10.1002/1099-0690(200012)2000:24<4011::AID-EJOC4011>3.0.CO

[2]

2-D

[3]

ARENA CG, 1992, INORG CHEM, V31, P4797

[4] New phosphoramidite and phosphito-N chiral ligands based on 8-substituted quinolines and (S)-binaphthol;: applications in the Cu-catalyzed enantioselective conjugate addition of diethylzinc to 2-cyclohexen-1-one [J].