Complexes of copper(II) with the β-blocker atenolol

被引：19

作者：

Bontchev, PR

Pantcheva, IN

Gochev, GP

Mehandjiev, DR

Ivanov, DS

机构：

[1] Univ Sofia, Fac Chem, Sofia 1164, Bulgaria

[2] Bulgarian Acad Sci, Inst Inorgan Chem, BG-1040 Sofia, Bulgaria

[3] Med Univ Sofia, Fac Pharm, Sofia, Bulgaria

来源：

TRANSITION METAL CHEMISTRY | 2000年 / 25卷 / 02期

关键词：

D O I：

10.1023/A:1007004517577

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mono- and binuclear copper(II) complexes with atenolol (HAt) can be obtained, depending on the reaction conditions. The mononuclear violet complex cation has the general formula Cu(HAt)(4)(2+) with an elongated octahedral geometry. The two ligands in the equatorial plane are bound in a bidentate fashion through the hydroxyl oxygen and amino nitrogen, while the other two atenolol molecules in axial position are coordinated in a monodentate way. The binuclear green complex Cu2At2Cl2, is neutral, where atenolol acts as a bidentate (O-, NH) bridging ligand. The bridge between the two Cu atoms is realized by the deprotonated oxygen of the alcohol group.

引用

页码：196 / 199

页数：4

共 29 条

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[2]

ANDERSON OP, 1973, J CHEM SOC DA, P1273

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