Syntheses and structures of new organoaluminum fluorides

被引：16

作者：

Hatop, H ^{[1
]}

Roesky, HW ^{[1
]}

Labahn, T ^{[1
]}

Fischer, A ^{[1
]}

Schmidt, HG ^{[1
]}

Noltemeyer, M ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 05期

关键词：

D O I：

10.1021/om990731b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper reports the synthesis of (Cp2ZrMe)(mu-F)[(Me3Si)(3)CAlF2] (1), [(Cp2Zr)(mu-F)(2)[(Me3Si)(3)CAlF]](2)O (2), and [Na(Me3Si)(3)CAlF3(THF)(])4 (3). 1 was prepared by the reaction of [(M(3)eSi)(3)CAlF2](3) with Cp2ZrMe2 and Me3SnF. Compound 1 reacts with THF to form 2. The reaction of (Me3Si)(3)CAlMe2(THF) with Me3SnF and NaCl affords 3. The molecular structures of compounds 1-3 have been determined by single-crystal X-ray structural analysis.

引用

页码：937 / 940

页数：4

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