The synthesis of organic carbonates from carbon dioxide

被引：985

作者：

Sakakura, Toshiyasu ^{[1
,2
]}

Kohno, Kazufumi ^{[1
]}

机构：

[1] AIST, Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 11期

关键词：

ONE-POT SYNTHESIS; ALKYLIDENE CYCLIC CARBONATES; CATALYZED COUPLING REACTION; DIMETHYL CARBONATE; PROPYLENE CARBONATE; CHEMICAL FIXATION; HIGHLY EFFICIENT; ETHYLENE-OXIDE; IONIC LIQUIDS; HETEROGENEOUS CATALYST;

D O I：

10.1039/b819997c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbon dioxide (CO2) is an easily available, renewable carbon resource, which has the advantages of being non-toxic, abundant and economical. CO2 is also attractive as an environmentally friendly chemical reagent, and is especially useful as a phosgene substitute. CO2 is an "anhydrous carbonic acid'' that rapidly reacts with basic compounds. Nucleophilic attack at CO2 conveniently produces carboxyl and carbamoyl groups. Further reactions of these species with electrophiles lead to the formation of organic carbonates and carbamates. The present article deals with the synthetic technologies leading to organic carbonates using CO2 as a raw material.

引用

页码：1312 / 1330

页数：19

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