Synthesis, characterization, and ion-exchange properties of zinc and magnesium manganese oxides confined within MCM-41 channels

被引：66

作者：

Aronson, BJ ^{[1
]}

Blanford, CF ^{[1
]}

Stein, A ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2000年 / 104卷 / 03期

关键词：

D O I：

10.1021/jp9920343

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zinc- and magnesium-manganese oxide particles have been grown in the pores of MCM-41 using a procedure adapted from a mild synthesis for layered manganese oxides. The Mn-modified silicates were analyzed by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), N-2 sorption, infrared (IR) spectroscopy, diffuse reflectance ultraviolet-visible (DRUV-vis) spectroscopy, electron spin resonance (ESR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA), and the ion-exchange and electrochemical properties were tested. The occluded manganese oxide consisted of well-dispersed, multivalent particles with a weakly ordered or amorphous structure. Ion-exchange studies determined that the occluded manganese oxide was more accessible to exchanging ions than bulk-layered manganese oxides prepared by a similar synthesis.

引用

页码：449 / 459

页数：11

共 69 条

[21] FORMATION AND STABILITY OF NI(I) IONS IN MCM-41 MESOPOROUS MOLECULAR-SIEVES
HARTMANN, M
POPPL, A
KEVAN, L
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (49) : 17494 - 17496
[22] X-RAY PHOTOELECTRON-SPECTROSCOPY OF NICKEL MANGANESE OXIDE THERMISTORS
HASHEMI, T
BRINKMAN, AW
[J]. JOURNAL OF MATERIALS RESEARCH, 1992, 7 (05) : 1278 - 1282
[23] Synthesis of macroporous minerals with highly ordered three-dimensional arrays of spheroidal voids
Holland, BT
Blanford, CF
Stein, A
[J]. SCIENCE, 1998, 281 (5376) : 538 - 540
[24] Synthesis of highly ordered, three-dimensional, macroporous structures of amorphous or crystalline inorganic oxides, phosphates, and hybrid composites
Holland, BT
Blanford, CF
Do, T
Stein, A
[J]. CHEMISTRY OF MATERIALS, 1999, 11 (03) : 795 - 805
[25] Effect of micropore topology on the structure and properties of zeolite polymer replicas
Johnson, SA
Brigham, ES
Ollivier, PJ
Mallouk, TE
[J]. CHEMISTRY OF MATERIALS, 1997, 9 (11) : 2448 - 2458
[26] Electrochemical intercalation of alkali-metal ions into birnessite-type manganese oxide in aqueous solution
Kanoh, H
Tang, WP
Makita, Y
Ooi, K
[J]. LANGMUIR, 1997, 13 (25) : 6845 - 6849
[27] Characterization of Al2O3-supported manganese oxides by electron spin resonance and diffuse reflectance spectroscopy
Kijlstra, WS
Poels, EK
Bliek, A
Weckhuysen, BM
Schoonheydt, RA
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (03): : 309 - 316
[28] LONG-LIVED LIGHT-INDUCED CHARGE SEPARATION IN A ZEOLITE L-BASED MOLECULAR TRIAD
KRUEGER, JS
MAYER, JE
MALLOUK, TE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (24) : 8232 - 8234
[29] KRUEGER JS, 1990, J INCL PHENOM MACRO, P365
[30] KRUEGER JS, 1991, SURF SCI SER, V38, P461

← 1 2 3 4 5 6 7 →