Defect-induced acceleration of a solid-state chemical reaction in zinc alkoxide single crystals

被引：20

作者：

Schön, E ^{[1
]}

Plattner, DA ^{[1
]}

Chen, P ^{[1
]}

机构：

[1] ETH, Organ Chem Lab, CH-8092 Zurich, Switzerland

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 10期

关键词：

D O I：

10.1021/ic030341o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of dinuclear (salicylaldimato)zinc(mu(2)-alkoxide) complexes show unusual behavior, decomposing to olefins and the corresponding mu(2)-hydroxide complexes under very mild conditions in the solid state. The reaction in homogeneous solution is, on the other hand, not observable, even at elevated temperatures over extended periods of time. The reaction in the solid state occurs preferentially on one crystallographic face and displays kinetics characteristic of polymorphic transformations in single crystals.

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页码：3164 / 3169

页数：6

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