High-k dielectrics for future generation memory devices (Invited Paper)

被引:215
作者
Kittl, J. A. [1 ]
Opsomer, K. [1 ]
Popovici, M. [1 ]
Menou, N. [1 ]
Kaczer, B. [1 ]
Wang, X. P. [1 ]
Adelmann, C. [1 ]
Pawlak, M. A. [1 ]
Tomida, K. [1 ]
Rothschild, A. [1 ]
Govoreanu, B. [1 ]
Degraeve, R. [1 ]
Schaekers, M. [1 ]
Zahid, M. [1 ]
Delabie, A. [1 ]
Meersschaut, J. [1 ]
Polspoel, W. [1 ]
Clima, S. [1 ]
Pourtois, G. [1 ]
Knaepen, W. [2 ]
Detavernier, C. [2 ]
Afanas'ev, V. V. [3 ]
Blomberg, T. [4 ]
Pierreux, D. [5 ]
Swerts, J. [5 ]
Fischer, P. [5 ]
Maes, J. W. [5 ]
Manger, D. [6 ]
Vandervorst, W. [1 ]
Conard, T. [1 ]
Franquet, A. [1 ]
Favia, P. [1 ]
Bender, H. [1 ]
Brijs, B. [1 ]
Van Elshocht, S. [1 ]
Jurczak, M. [1 ]
Van Houdt, J. [1 ]
Wouters, D. J. [1 ]
机构
[1] IMEC, B-3001 Leuven, Belgium
[2] Univ Ghent, Dept Solid State Sci, B-9000 Ghent, Belgium
[3] Katholieke Univ Leuven, Dept Phys & Astron, B-3001 Leuven, Belgium
[4] ASM Microchem, Helsinki 00560, Finland
[5] ASM Belgium, B-3001 Leuven, Belgium
[6] Qimonda, B-3001 Leuven, Belgium
关键词
High-k; DRAM; Flash; SrTiO3; ATOMIC LAYER DEPOSITION; KAPPA GATE DIELECTRICS; SRTIO3; THIN-FILMS; ELECTRICAL-PROPERTIES;
D O I
10.1016/j.mee.2009.03.045
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The requirements and development of high-k dielectric films for application in storage cells of future generation flash and Dynamic Random Access Memory (DRAM) devices are reviewed. Dielectrics with k-value in the 9-30 range are studied as insulators between charge storage layers and control gates in flash devices. For this application, large band gaps (>6 eV) and band offsets are required, as well as low trap densities. Materials studied include aluminates and scandates. For DRAM metal-insulator-metal (MIM) capacitors, aggressive scaling of the equivalent oxide thickness (with targets down to 0.3 nm) drives the research towards dielectrics with k-values >50. Due to the high aspect ratio of MIMCap structures, highly conformal deposition techniques are needed, triggering a substantial effort to develop Atomic Layer Deposition (ALD) processes for the deposition of metal gates and high-k dielectrics. Materials studied include Sr- and Ba-based perovskites, with SrTiO3 as one of the most promising candidates, as well as tantalates, titanates and niobates. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1789 / 1795
页数:7
相关论文
共 26 条
[1]   Thermal stability of dysprosium scandate thin films [J].
Adelmann, C. ;
Van Elshocht, S. ;
Franquet, A. ;
Conard, T. ;
Richard, O. ;
Bender, H. ;
Lehnen, P. ;
De Gendt, S. .
APPLIED PHYSICS LETTERS, 2008, 92 (11)
[2]   Internal photoemission at interfaces of high-κ insulators with semiconductors and metals [J].
Afanas'ev, V. V. ;
Stesmans, A. .
JOURNAL OF APPLIED PHYSICS, 2007, 102 (08)
[3]   Increment of dielectric properties of SrTiO3 thin films by SrO interlayer on Ru bottom electrodes [J].
Ahn, Ji-Hoon ;
Kim, Ja-Yong ;
Kang, Sang-Won .
APPLIED PHYSICS LETTERS, 2007, 91 (06)
[4]  
Degraeve R, 2008, INT EL DEVICES MEET, P775
[5]   Performance and reliability of HfAlOx-based interpoly dielectrics for floating-gate Flash memory [J].
Govoreanu, B. ;
Wellekens, D. ;
Haspeslagh, L. ;
Brunco, D. P. ;
De Vos, J. ;
Aguado, D. Ruiz ;
Blomme, P. ;
van der Zanden, K. ;
Van Houdt, J. .
SOLID-STATE ELECTRONICS, 2008, 52 (04) :557-563
[6]   Understanding the potential and limitations of HfAlO as interpoly dielectric in floating-gate Flash memory [J].
Govoreanu, B. ;
Degraeve, R. ;
Zahid, M. B. ;
Nyns, L. ;
Cho, M. ;
Kaczer, B. ;
Jurczak, M. ;
Kittl, J. A. ;
Van Houdt, J. .
MICROELECTRONIC ENGINEERING, 2009, 86 (7-9) :1807-1811
[7]   Electrical properties of high-κ gate dielectrics:: Challenges, current issues, and possible solutions [J].
Houssa, M. ;
Pantisano, L. ;
Ragnarsson, L. -A. ;
Degraeve, R. ;
Schram, T. ;
Pourtois, G. ;
De Gendt, S. ;
Groeseneken, G. ;
Heyns, M. M. .
MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2006, 51 (4-6) :37-85
[8]   DEPOSITION OF EXTREMELY THIN (BA,SR)TIO3 THIN-FILMS FOR ULTRA-LARGE-SCALE INTEGRATED DYNAMIC RANDOM-ACCESS MEMORY APPLICATION [J].
HWANG, CS ;
PARK, SO ;
CHO, HJ ;
KANG, CS ;
KANG, HK ;
LEE, SI ;
LEE, MY .
APPLIED PHYSICS LETTERS, 1995, 67 (19) :2819-2821
[9]  
Kil D-S., 2006, Symposium on VLSI Tech. Dig, P38
[10]   Atomic layer deposition and electrical properties of SrTiO3 thin films grown using Sr(C11H19O2)2, Ti(Oi-C3H7)4, and H2O [J].
Kwon, Oh Seong ;
Lee, Sang Woon ;
Han, Jeong Hwan ;
Hwang, Cheol Seong .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2007, 154 (06) :G127-G133