Hypervalent iodine reagents in organic synthesis: Nucleophilic substitution of p-substituted phenol ethers

被引：188

作者：

Kita, Y

Takada, T

Tohma, T

机构：

[1] Faculty of Pharmaceutical Sciences, Osaka University, Suita, Osaka 565

来源：

PURE AND APPLIED CHEMISTRY | 1996年 / 68卷 / 03期

关键词：

D O I：

10.1351/pac199668030627

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel hypervalent iodine-induced nucleophilic substitution of p-substituted phenol ethers in the presence of a variety of nucleophiles and the direct alkyl azidation of p-alkyl phenol ethers are described UV and ESR spectroscopic studies indicate that these reactions proceed via radical species; one is [ArH+.] and the other is [ArC(.)R(1)R(2)] as reactive intermediates.

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页码：627 / 630

页数：4

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