P,N-heterodifunctional ligands by selective Staudinger reaction of β-substituted vinylazides with (Z)-1,2-bis(diphenylphosphanyl)-ethene and formation of cyclometalled complexes of palladium(II) of these ligands -: crystal and molecular structure of a new chiral cyclometallaphosphoraniminophosphane of palladium(II)

被引：14

作者：

Arques, A

Molina, P

Auñón, D

Vilaplana, MJ

Velasco, MD

Martínez, F

Bautista, D

Lahoz, FJ

机构：

[1] Univ Murcia, Fac Quim, Dept Quim Organ, E-30071 Murcia, Spain

[2] Univ Murcia, Fac Quim, Dept Quim Fis, E-30071 Murcia, Spain

[3] Univ Murcia, SACE, E-30071 Murcia, Spain

[4] Univ Zaragoza, Fac Ciencias, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 598卷 / 02期

关键词：

beta-arylvinyl azides; beta-ferrocenylvinylazide; (Z)-1,2-bis(diphenylphosphanyl)ethene; P; N-difunctional ligands; cyclometalled complexes; palladium; X-ray structure analysis;

D O I：

10.1016/S0022-328X(99)00731-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Staudinger reactions of the beta-aryl-, heteroaryl- and ferrocenylvinylazides (2) with (Z)-1,2-bis(diphenylphosphanyl)ethene afford the P,N-ligands (3) in good yields. Reaction of 3 with dichlorobis(benzonitrile)palladium(II) leads to the Pd(II) metallacycle derivatives 5. The molecular structure of 5e has been determined by X-ray crystallography. The electrochemical behavior of this compound is also reported. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：329 / 338

页数：10

共 45 条

[31] PALLADIUM(II) AND PLATINUM(II) COMPLEXES OF CIS-1,2-BIS(DIPHENYLPHOSPHINO) ETHENE - COMPLETELY PLANAR STRUCTURES DUE TO PI-BONDING IN THE CASE OF PLATINUM(II) [J].