Emission characteristics of CdS nanoparticles induced by confinement within MCM-41 nanotubes

被引：65

作者：

Chae, WS ^{[1
]}

Ko, JH ^{[1
]}

Hwang, IW ^{[1
]}

Kim, YR ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seodaemun Gu, Seoul 120749, South Korea

来源：

CHEMICAL PHYSICS LETTERS | 2002年 / 365卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(02)01418-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nanosize CdS particles confined in siliceous MCM-41 channels were prepared by using reversed micelles as an insertion carrier. As-made CdS in MCM-41 host shows photoluminescence (PL) signals from both band-edge and surface defect state recombination. Calcinated CdS in the host, however, presents relatively suppressed surface defect state emission compared with band-edge emission. Such emission characteristics after calcination is ascribed to the reduced probability of recombination through deeply trapped surface defect states compared with direct excitonic recombination, which is possibly due to surface capping of the CdS nanoparticles by the host nanochannels. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：49 / 56

页数：8

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