Synthesis and immobilization of N-heterocyclic carbene complexes of Ru(II):: catalytic activity and recyclability for the furan formation

被引：70

作者：

Çetinkaya, B

Gürbüz, N

Seçkin, T

Özdemir, I

机构：

[1] Ege Univ, Dept Chem, TR-35100 Bornova, Turkey

[2] Inonu Univ, Dept Chem, Malatya, Turkey

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2002年 / 184卷 / 1-2期

关键词：

N-heterocyclic carbenes; ruthenium complexes; immobilization; catalysts for furan formation;

D O I：

10.1016/S1381-1169(01)00527-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Synthesis, characterization and immobilization of ruthenium(II) complexes of the type [RuCl2L(eta(6)-arene)] (L=CN(CH2PH)CH2CH2N(CH2)(3)Si(OEt)(3), arene = p-cymene, 3 and arene = C6Me6, 4) and [RuCl2L] (L = eta(1)-carbene-eta(6)-arene bidentate ligand, CN[(CH2)(3)Si(OEt)(3)]CH2CH2NCH2C6H2Me3-eta(6)), 5, morphologically different silicas by sol-gel method are described and their reactivity and recyclability in the furan formation were also reported. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：31 / 38

页数：8

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