Asymmetric hydrogenation, transfer hydrogenation and hydrosilylation of ketones catalyzed by iron complexes

被引：672

作者：

Morris, Robert H. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

N-N-P; BIOMIMETIC TRANSFER HYDROGENATION; RAY CRYSTAL-STRUCTURE; SELECTIVE HYDROGENATION; TETRADENTATE LIGAND; MECHANISTIC ASPECTS; CARBONYL-COMPOUNDS; RUTHENIUM HYDRIDE; EFFICIENT; METAL;

D O I：

10.1039/b806837m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conventional homogeneous catalysts for the enantioselective hydrogenation or transfer hydrogenation of ketones are based on platinum metals and, in particular, ruthenium. This method provides valuable enantiopure alcohols for the fine chemical industries. This tutorial review summarizes recent successes in replacing expensive and toxic ruthenium in these catalysts with "greener'' iron substitutes including my lab's recent progress in this area using iron complexes containing readily-prepared tetradentate ligands. It will enlighten chemists interested in homogeneous catalysis and asymmetric synthesis.

引用

页码：2282 / 2291

页数：10

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