A new efficient route for the formation of quinoxaline N-oxides and N,N′-dioxides using HOF•CH3CN

被引：31

作者：

Carmeli, Mira ^{[1
]}

Rozen, Shlomo ^{[1
]}

机构：

[1] Tel Aviv Univ, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 15期

关键词：

D O I：

10.1021/jo0608016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

HOF center dot CH3CN, a very efficient oxygen-transfer agent made readily from fluorine and aqueous acetonitrile, was reacted with various quinoxaline derivatives to give the corresponding mono N-oxides and especially the N,N'-dioxides in very good yields under mild conditions and short reaction times.

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页码：5761 / 5765

页数：5

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