Synthesis, Crystal Structure and Luminescent Properties of One Cadmium(II) Coordination Polymer with Mixed Thiocyanate and Quinoline Ligands

被引：8

作者：

Bai, Yan ^{[1
]}

Gao, Hui ^{[1
]}

Dang, Dong-Bin ^{[1
]}

Hu, Xue-Fu ^{[1
]}

Guo, Xiang-Yang ^{[1
]}

机构：

[1] Henan Univ, Sch Chem & Chem Engn, Inst Mol & Crystal Engn, Kaifeng 475004, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Cadmium(II) complex; crystal structure; luminescent properties; thiocyanato bridged; ELEMENTAL COPPER; ETHYLENEDIAMINE; COMPLEX; CHAIN;

D O I：

10.1080/15533170903324650

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel Cd(II) coordination polymer [Cd(SCN)2(ql)2]2 center dot (CH3CN)2 (ql = quinoline) has been synthesized and characterized by IR, UV, elemental analysis and X-ray crystallography. Cd(II) atom has an distorted octahedral environment with an N4S2 donor set. A pair of 1,3--SCN- anions bridge two adjacent Cd(II) centers to form one dimension chain structure. A 1D structure is held together with its neighboring ones via - stacking interactions to form a 3D supramolecular structure. The luminescent properties of the title complex at room temperature were investigated.

引用

页码：512 / 515

页数：4

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