Chemical and Physical Solutions for Hydrogen Storage

被引：1299

作者：

Eberle, Ulrich ^{[2
]}

Felderhoff, Michael ^{[1
]}

Schueth, Ferdi ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

[2] Adam Opel GmbH, GM Alternat Prop Ctr, Hydrogen Fuel Cell & Elect Prop Res Strategy, D-65423 Russelsheim, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 36期

关键词：

adsorption; hydrides; hydrogen; hydrogen storage; reforming; WATER-GAS-SHIFT; METAL-ORGANIC FRAMEWORKS; SELECTIVE CO OXIDATION; DOPED SODIUM ALANATE; GASOLINE FUEL PROCESSOR; AUXILIARY POWER UNITS; X-RAY-ABSORPTION; THERMAL-DECOMPOSITION; PREFERENTIAL OXIDATION; CRYSTAL-STRUCTURE;

D O I：

10.1002/anie.200806293

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen is a promising energy carrier in future energy systems. However, storage of hydrogen is a substantial challenge, especially for applications in vehicles with fuel cells that use proton-exchange membranes (PEMs). Different methods for hydrogen storage are discussed, including high-pressure and cryogenic-liquid storage, adsorptive storage on high-surface-area adsorbents, chemical storage in metal hydrides and complex hydrides, and storage in boranes. For the latter chemical solutions, reversible options and hydrolytic release of hydrogen with off-board regeneration are both possible. Reforming of liquid hydrogen-containing compounds is also a possible means of hydrogen generation. The advantages and disadvantages of the different systems are compared. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：6608 / 6630

页数：23

共 185 条

[61] Molecular aluminum hydrides identified by inelastic neutron scattering during H2 regeneration of catalyst-doped NaAlH4
Fu, QJ
Ramirez-Cuesta, AJ
Tsang, SC
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (02) : 711 - 715
[62] Ghenciu AF, 2002, CURR OPIN SOLID ST M, V6, P389, DOI 10.1016/S1359-0286(02)00108-0
[63] X-ray absorption study of Ti-activated sodium aluminum hydride
Graetz, J
Reilly, JJ
Johnson, J
Ignatov, AY
Tyson, TA
[J]. APPLIED PHYSICS LETTERS, 2004, 85 (03) : 500 - 502
[64] Lithium nitrides, imides and amides as lightweight, reversible hydrogen stores
Gregory, Duncan H.
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (20) : 2321 - 2330
[65] Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen
Grochala, W
Edwards, PP
[J]. CHEMICAL REVIEWS, 2004, 104 (03) : 1283 - 1315
[66] Gutowska A., 2005, ANGEW CHEM, V117, P3644
[67] Improved designs of metal-organic frameworks for hydrogen storage
Han, Sang Soo
Deng, Wei-Qiao
Goddard, William A., III
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (33) : 6289 - 6292
[68] Lithium-doped metal-organic frameworks for reversible H2 storage at ambient temperature
Han, Sang Soo
Goddard, William A., III
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (27) : 8422 - +
[69] Kinetic study of selective CO oxidation in H2-rich gas on a Ru/γ-Al2O3 catalyst
Han, YF
Kahlich, MJ
Kinne, M
Behm, RJ
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2002, 4 (02) : 389 - 397
[70] Comparison of the calculated and experimental scenarios for solid-state reactions involving Ca(AIH4)2
Hanada, Nobuko
Lohstroh, Wiebke
Fichtner, Maximilian
[J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (01) : 131 - 138

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