Synthesis of 1-azaazulenes from cycloheptatrienylmethyl ketone O-pentafluorobenzoyloximes by palladium-catalyzed cyclization and oxidation

被引：56

作者：

Chiba, S ^{[1
]}

Kitamura, M ^{[1
]}

Saku, O ^{[1
]}

Narasaka, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2004年 / 77卷 / 04期

关键词：

D O I：

10.1246/bcsj.77.785

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various 1-azaazulenes are synthesized from cycloheptatrienylmethyl ketone O-pentafluorobenzoyloximes by treatment,with a catalytic amount of Pd(dba)(2)-t-Bu3P (dba = dibenzylideneacetone) and triethylamine in the presence of MS 4A via alkylideneaminopalladium(II) intermediates generated by oxidative addition of the oximes to a Pd(0) complex.

引用

页码：785 / 796

页数：12