Solution synthesis of ultrastable luminescent siloxane-coated silicon nanoparticles

被引:214
作者
Zou, J [1 ]
Baldwin, RK [1 ]
Pettigrew, KA [1 ]
Kauzlarich, SM [1 ]
机构
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
关键词
D O I
10.1021/nl0497373
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Silicon nanoparticles (NPs) of similar to4.5(1.10) nm from a room-temperature solution route are terminated by a silanization method for the first time. Energy-selected emission is observed, consistent with the distribution of sizes obtained by this route. The NPs are photochemically stable in nonpolar organic solvents and when exposed to air/water under ambient conditions for up to 1 year. The nanoparticles were characterized by TEM, HRTEM, EDX, SAED, FTIR, H-1/C-13 NMR, UV-vis, and photoluminescence (PL) spectroscopy.
引用
收藏
页码:1181 / 1186
页数:6
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