Syntheses, crystal structures, and luminescent properties of novel layered lanthanide sulfonate-phosphonates

被引：150

作者：

Song, JL ^{[1
]}

Lei, C ^{[1
]}

Mao, JG ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 18期

关键词：

D O I：

10.1021/ic049376u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Hydrothermal reactions of lanthanide metal salts with MeN(CH2CO2H)(CH2PO3H2) (H3L) and 5-sulfoisophthalic acid monosodium salt (NaH2BTS) lead to four isomorphous lanthanide carboxylate-phosphonate-sulfonate hybrids, namely, Ln(H2L)(HBTS)(H2O)(2).H2O (Ln = La (1), Pr (2), Nd (3), Gd (4)). Their structures have been established by X-ray single-crystal diffraction. The interconnection of the lanthanide(III) ions by carboxylate-phosphonate ligands results in a 1D double chain; these double chains are further bridged by bidentate bridging carboxylate-sulfonate ligands to form a <011> layer. The luminescent properties of compounds 3 and 4 have also been studied.

引用

页码：5630 / 5634

页数：5

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