Investigation of the sulfur speciation in petroleum products by capillary gas chromatography with ICP-collision cell-MS detection

被引：32

作者：

Bouyssiere, B

Leonhard, P

Pröfrock, D

Baco, F

Garcia, CL

Wilbur, S

Prange, A

机构：

[1] CNRS, UMR 5034, F-64053 Pau, France

[2] GKSS Forschungszentrum Geesthacht GmbH, Inst Coastal Res Phys & Chem Anal, D-21502 Geesthacht, Germany

[3] CEDI Rene Navarre, Inst Francais Petr, Vernaison, France

[4] Agilent Technol Inc, Bellevue, WA 98007 USA

来源：

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 2004年 / 19卷 / 05期

关键词：

D O I：

10.1039/b310449d

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Recent regulations concerning the low-sulfur gasoline require analytical methods able to provide specific information on sulfur containing compounds present in petroleum products at the ng g(-1) range. The on-line coupling of capillary GC with ICP-collision cell-MS was proposed for the speciation of sulfur in hydrocarbon matrices. The technique showed an absolute detection limit 0.5 pg for a 1 muL sample injected in the splitless mode which is about two orders of magnitude lower than the currently used techniques.

引用

收藏

页码：700 / 702

页数：3

相关论文

共 26 条

[1] POLYCYCLIC AROMATIC SULFUR HETEROCYCLES .4. DETERMINATION OF POLYCYCLIC AROMATIC-COMPOUNDS IN A SHALE OIL WITH THE ATOMIC-EMISSION DETECTOR [J].

ANDERSSON, JT ;

SCHMID, B .

JOURNAL OF CHROMATOGRAPHY A, 1995, 693 (02) :325-338

[2] Elementary analysis of petroleum distillates by GC-AED: Validation and application to the calculation of distillation profile properties [J].

Baco, F ;

Quignard, A ;

Szymanski, R .

OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES, 1999, 54 (04) :473-485

[3] Speciation analysis for mercury in gas condensates by capillary gas chromatography with inductively coupled plasma mass spectrometric detection [J].

Bouyssiere, B ;

Baco, F ;

Savary, L ;

Lobiñski, R .

JOURNAL OF CHROMATOGRAPHY A, 2002, 976 (1-2) :431-439

[4] Gas chromatography with inductively coupled plasma mass spectrometric detection in speciation analysis [J].

Bouyssiere, B ;

Szpunar, J ;

Lobinski, R .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 2002, 57 (05) :805-828

[5] Investigation of speciation of arsenic in gas condensates by capillary gas chromatography with ICP-MS detection [J].

Bouyssiere, B ;

Baco, F ;

Savary, L ;

Garraud, H ;

Gallup, DL ;

Lobinski, R .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2001, 16 (11) :1329-1332

[6] Molecular analysis of the sulphur components in a light cycle oil of a catalytic cracking unit by gas chromatography with mass spectrometric and atomic emission detection [J].

Depauw, GA ;

Froment, GF .

JOURNAL OF CHROMATOGRAPHY A, 1997, 761 (1-2) :231-247

[7]

DISANZO FP, 1994, HRC-J HIGH RES CHROM, V17, P255

[8] ANALYSIS OF GEOPORPHYRINS BY HIGH-TEMPERATURE GAS-CHROMATOGRAPHY INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY AND HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY [J].

EBDON, L ;

EVANS, EH ;

PRETORIUS, WG ;

ROWLAND, SJ .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1994, 9 (09) :939-943

[9] COMPARISON OF COMMERCIALLY AVAILABLE ATOMIC EMISSION AND CHEMILUMINESCENCE DETECTORS FOR SULFUR-SELECTIVE GAS-CHROMATOGRAPHIC DETECTION [J].

ECKERTTILOTTA, SE ;

HAWTHORNE, SB ;

MILLER, DJ .

JOURNAL OF CHROMATOGRAPHY, 1992, 591 (1-2) :313-323

[10] Analysis of aromatic sulfur compounds in gas oils using GC with sulfur chemiluminescence detection and high-resolution MS [J].

García, CL ;

Becchi, M ;

Grenier-Loustalot, MF ;

Païsse, O ;

Szymanski, R .

ANALYTICAL CHEMISTRY, 2002, 74 (15) :3849-3857