Threading dislocations in epitaxial ferroelectric PbZr0.2Ti0.8O3 films and their effect on polarization backswitching

被引:61
作者
Vrejoiu, I. [1 ]
Le Rhun, G. [1 ]
Zakharov, N. D. [1 ]
Hesse, D. [1 ]
Pintilie, L. [1 ]
Alexe, M. [1 ]
机构
[1] Max Planck Inst Microstruct Phys, D-06120 Halle, Salle, Germany
关键词
D O I
10.1080/14786430600728653
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The existence of threading dislocations in ferroelectric heterostructures has been frequently reported. However, their origin and impact on the ferroelectric properties are not sufficiently understood. PbZr0.2Ti0.8O3/SrRuO3 heterostructures were epitaxially grown by pulsed-laser deposition (PLD) onto vicinal SrTiO3(001) substrates. The threading dislocations exhibited by the PbZr0.2Ti0.8O3 films were investigated by cross-sectional and plan-view (high-resolution) transmission electron microscopy. Many threading dislocations were dissociated into dipoles spanning a, most probably lead-rich, stacking fault. It is likely that these dislocations are able to pin 180 degrees ferroelectric domains, as suggested by a comparison between piezo-force microscope and transmission electron micrographs obtained on identical samples. Local backswitching of the polarization was observed in the vicinity of such threading dislocations.
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收藏
页码:4477 / 4486
页数:10
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