Circular dichroism induced by helical host molecules

被引：8

作者：

Kodaka, M

机构：

[1] Biomolecules Department, National Institute of Bioscience and Human-Technology, Tsukuba, Ibaraki 305

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1997年 / 93卷 / 11期

关键词：

D O I：

10.1039/a700222j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Induced circular dichroism (ICD) of a guest chromophore included inside the cavity of a helical host molecule has been calculated using the coupled oscillator model, where the guest molecule was assumed to be located in the centre of the cavity. ICD depends on the length of a helical host; i.e., as the length of the helix increases, the ICD value increases (or decreases) and passes a maximum (or a minimum) and then approaches zero.

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页码：2057 / 2059

页数：3

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