Phosphonium-Based Ionic Liquids: An Overview

被引：447

作者：

Fraser, Kevin J. ^{[1
]}

MacFarlane, Douglas R. ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Wellington, Vic 3800, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2009年 / 62卷 / 04期

关键词：

CROSS-COUPLING REACTIONS; QUATERNARY PHOSPHONIUM; ELECTROCHEMICAL PROPERTIES; PHYSICOCHEMICAL PROPERTIES; POTENTIAL APPLICATION; MAGNESIUM ALLOYS; HECK REACTIONS; MOLTEN-SALTS; ARYL HALIDES; ELECTROLYTES;

D O I：

10.1071/CH08558

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphonium cation-based ionic liquids (ILs) are a readily available family of ILs that in some applications offer superior properties as compared to nitrogen cation-based ILs. Applications recently investigated include their use as extraction solvents, chemical synthesis solvents, electrolytes in batteries and super-capacitors, and in corrosion protection. At the same time the range of cation-anion combinations available commercially has also been increasing in recent years. Here, we provide an overview of the properties of these interesting materials and the applications in which they are appearing.

引用

页码：309 / 321

页数：13

共 173 条

[81] Dye-sensitized solar cells based on quaternary phosphonium ionic liquids as electrolytes [J].

Kunugi, Yoshihito ;

Hayakawa, Hideyuki ;

Tsunashima, Katsuhiko ;

Sugiya, Masashi .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2007, 80 (12) :2473-2475

[82]

LaboratoriBaldacci S. p. A., 1984, [No title captured], Patent No. [JP59046268, 59046268]

[83] STABILITY OF QUATERNARY ONIUM SALTS UNDER PHASE-TRANSFER CONDITIONS IN THE PRESENCE OF AQUEOUS ALKALINE-SOLUTIONS [J].

LANDINI, D ;

MAIA, A ;

RAMPOLDI, A .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (16) :3187-3191

[84] NON-HYDRATED ANION TRANSFER FROM THE AQUEOUS TO THE ORGANIC-PHASE - ENHANCEMENT OF NUCLEOPHILIC REACTIVITY IN PHASE-TRANSFER CATALYSIS [J].

LANDINI, D ;

MAIA, A ;

PODDA, G .

JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (12) :2264-2268

[85] Grignard reagents in ionic liquids [J].

Law, Man Chun ;

Wong, Kwok-Yin ;

Chan, Tak Hang .

CHEMICAL COMMUNICATIONS, 2006, (23) :2457-2459

[86]

Lee JS, 2004, J IND ENG CHEM, V10, P1086

[87] Activity coefficients at infinite dilution measurements for organic solutes in the ionic liquid trihexyltetradecylphosphonium-bis-(2,4,4-trimethylpentyl)-phosphinate using g.l.c. at T = (303.15, 308.15, 313.15, and 318.15) K [J].

Letcher, Trevor M. ;

Ramjugernath, Deresh ;

Laskowska, Marta ;

Krolikowski, Marek ;

Naidoo, Paramespri ;

Domanska, Urszula .

JOURNAL OF CHEMICAL THERMODYNAMICS, 2008, 40 (08) :1243-1247

[88] Formation of phosphate/permanganate conversion coating on AZ31 magnesium alloy [J].

Lin, CS ;

Lee, CY ;

Li, WC ;

Chen, YS ;

Fang, GN .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (03) :B90-B96

[89] Use of ionic liquids for π-conjugated polymer electrochemical devices [J].

Lu, W ;

Fadeev, AG ;

Qi, BH ;

Smela, E ;

Mattes, BR ;

Ding, J ;

Spinks, GM ;

Mazurkiewicz, J ;

Zhou, DZ ;

Wallace, GG ;

MacFarlane, DR ;

Forsyth, SA ;

Forsyth, M .

SCIENCE, 2002, 297 (5583) :983-987

[90] Electrochemical actuator devices based on polyaniline yarns and ionic liquid electrolytes [J].

Lu, W ;

Norris, ID ;

Mattes, BR .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2005, 58 (04) :263-269

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