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[31]
Tulloch A.A.D., 2003, J CHEM SOC DA, P699
Microwave-assisted Suzuki-Miyaura reactions with an insoluble pyridine-aldoxime Pd-catalyst
被引：60
作者：
Solodenko, W
Schön, U
Messinger, J
Glinschert, A
Kirschning, A
机构：
[1] Univ Hannover, Zentrum Organ Chem, D-30167 Hannover, Germany
[2] Solvay Pharmaceut Res Labs, D-30173 Hannover, Germany
来源：
关键词：
Suzuki-Miyaura reactions;
precatalyst;
pyridine-aldoxime Pd-catalyst;
D O I：
10.1055/s-2004-829546
中图分类号：
O62 [有机化学];
学科分类号：
070303 ;
081704 ;
摘要：
The preparation of a solid Pd(II)-precatalyst and its use in microwave-assisted Suzuki-Miyaura reactions in water is described. The precatalyst is obtained by treatment of 4-pyridine-aldoxime with Na2PdCl4 and is insoluble in organic solvents as well as in water. Its robustness under microwave conditions and its insolubility allows simple reuse in 'teabags'.
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页码：1699 / 1702
页数：4
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