Highly efficient and recyclable heterogeneous asymmetric transfer hydrogenation of ketones in water

被引：155

作者：

Liu, PN

Deng, JG

Tu, YQ ^{[1
]}

Wang, SH

机构：

[1] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China

[2] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China

[3] Chinese Acad Sci, Union Lab Asymmetr Synth, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 18期

关键词：

D O I：

10.1039/b408533g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient heterogeneous asymmetric transfer hydrogenation of ketones in water was developed for the first time, which exhibited excellent enantioselectivities, distinct acceleration effect and remarkably high recyclabilities.

引用

页码：2070 / 2071

页数：2

共 19 条

[1] Synthesis of water-soluble aminosulfonamide ligands and their application in enantioselective transfer hydrogenation
Bubert, C
Blacker, J
Brown, SM
Crosby, J
Fitzjohn, S
Muxworthy, JP
Thorpe, T
Williams, JMJ
[J]. TETRAHEDRON LETTERS, 2001, 42 (24) : 4037 - 4039
[2] Ordered mesoporous and microporous molecular sieves functionalized with transition metal complexes as catalysts for selective organic transformations
De Vos, DE
Dams, M
Sels, BF
Jacobs, PA
[J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3615 - 3640
[3] Recoverable catalysts for asymmetric organic synthesis
Fan, QH
Li, YM
Chan, ASC
[J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3385 - 3465
[4] Hydrophilic diamine ligands for catalytic asymmetric hydrogenation of C=O bonds
Ferrand, A
Bruno, M
Tommasino, ML
Lemaire, M
[J]. TETRAHEDRON-ASYMMETRY, 2002, 13 (13) : 1379 - 1384
[5] Sol-gel entrapped chiral rhodium and ruthenium complexes as recyclable catalysts for the hydrogenation of itaconic acid
Gelman, F
Avnir, D
Schumann, H
Blum, J
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 146 (1-2) : 123 - 128
[6] Aqueous enantioselective hydrogenations involving silica-heterogenised catalysts
Jamis, J
Anderson, JR
Dickson, RS
Campi, EM
Jackson, WR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 603 (01) : 80 - 85
[7] Stereoselective organic reactions in water
Lindström, UM
[J]. CHEMICAL REVIEWS, 2002, 102 (08) : 2751 - 2771
[8] Efficient heterogeneous asymmetric transfer hydrogenation of ketones using highly recyclable and accessible silica-immobilized Ru-TsDPEN catalysts
Liu, PN
Gu, PM
Wang, F
Tu, YQ
[J]. ORGANIC LETTERS, 2004, 6 (02) : 169 - 172
[9] Asymmetric transfer hydrogenation of prochiral ketones in aqueous media with new water-soluble chiral vicinal diamine as ligand
Ma, YP
Liu, H
Chen, L
Cui, X
Zhu, J
Deng, JE
[J]. ORGANIC LETTERS, 2003, 5 (12) : 2103 - 2106
[10] Recoverable catalysts and reagents using recyclable polystyrene-based supports
McNamara, CA
Dixon, MJ
Bradley, M
[J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3275 - 3299

← 1 2 →