Supported silver nanoparticle catalyst for selective hydration of nitriles to amides in water

被引：163

作者：

Mitsudome, Takato ^{[1
]}

Mikami, Yusuke ^{[1
]}

Mori, Haruhiko ^{[1
]}

Arita, Shusuke ^{[1
]}

Mizugaki, Tomoo ^{[1
]}

Jitsukawa, Koichiro ^{[1
]}

Kaneda, Kiyotomi ^{[1
,2
]}

机构：

[1] Osaka Univ, Dept Mat Engn Sci, Grad Sch Engn Sci, Osaka 5608531, Japan

[2] Osaka Univ, Res Ctr Solar Energy Chem, Osaka 5608531, Japan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 22期

关键词：

GOLD CATALYSTS; OXIDATION; HYDROGENATION; HYDROXYAPATITE; MECHANISM; ETHYLENE; COMPLEX;

D O I：

10.1039/b902469g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroxyapatite-supported silver nanoparticles (AgHAP) acted as a highly efficient reusable heterogeneous catalyst for hydration of diverse nitriles, including heteroaromatic ones, into amides in water.

引用

页码：3258 / 3260

页数：3

共 33 条

[1]

Bathina H. B., 1991, ENCY CHEM TECHNOLOGY, V1, P252

[2] A facile synthesis of amides by selective hydration of nitriles using modified natural phosphate and hydroxyapatite as new catalysts [J].

Bazi, F ;

El Badaoui, H ;

Tamani, S ;

Sokori, S ;

Solhy, A ;

Macquarrie, DJ ;

Sebti, S .

APPLIED CATALYSIS A-GENERAL, 2006, 301 (02) :211-214

[3]

Challis B. C., 1979, COMPREHENSIVE ORGANI, V2, P964

[4] Ag/SiO2:: A novel catalyst with high activity and selectivity for hydrogenation of chloronitrobenzenes [J].

Chen, YY ;

Wang, CA ;

Liu, HY ;

Qiu, JS ;

Bao, XH .

CHEMICAL COMMUNICATIONS, 2005, (42) :5298-5300

[5] Gold catalysts open a new general chemoselective route to synthesize oximes by hydrogenation of α,β-unsaturated nitrocompounds with H2 [J].

Corma, Avelino ;

Serna, Pedro ;

Garcia, Hermenegildo .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (20) :6358-+

[6] Chemoselective hydrogenation of nitro compounds with supported gold catalysts [J].

Corma, Avelino ;

Serna, Pedro .

SCIENCE, 2006, 313 (5785) :332-334

[7]

Feldheim DL, 2002, METAL NANOPARTICLES: SYNTHESIS, CHARACTERIZATION, AND APPLICATIONS, P1

[8] Dihydrogen-bond-promoted catalysis:: Catalytic hydration of nitriles with the indenylruthenium hydride complex (η5-C9H7)Ru(dppm)H (dppm = bis(diphenylphosphino)methane) [J].

Fung, WK ;

Huang, X ;

Man, ML ;

Ng, SM ;

Hung, MY ;

Lin, ZY ;

Lau, CP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) :11539-11544

[9] The catalytic hydration of nitriles to amides using a homogeneous platinum phosphinito catalyst [J].

Ghaffar, T ;

Parkins, AW .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 160 (02) :249-261

[10] RhI-catalyzed hydration of organonitriles under ambient conditions [J].

Goto, Akihiro ;

Endo, Kohei ;

Saito, Susumu .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (19) :3607-3609

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