Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-H aminations

被引：204

作者：

Reddy, Ravisekhara P. ^{[1
]}

Davies, Huw M. L. ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Univ Buffalo, Buffalo, NY 14260 USA

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 22期

关键词：

D O I：

10.1021/ol061742l

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dirhodium tetracarboxylate, Rh-2(S-TCPTAD)(4), derived from adamantylglycine, is an effective chiral catalyst for both inter- and intramolecular C-H aminations.

引用

页码：5013 / 5016

页数：4

共 67 条

[41] N-tosyloxycarbamates as a source of metal nitrenes:: Rhodium-catalyzed C-H insertion and aziridination reactions [J].

Lebel, H ;

Huard, K ;

Lectard, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (41) :14198-14199

[42] Nitrido ruthenium porphyrins: Synthesis, characterization, and amination reactions with hydrocarbon or silyl enol ethers [J].

Leung, SKY ;

Huang, JS ;

Liang, JL ;

Che, CM ;

Zhou, ZY .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (03) :340-+

[43] MECHANISM OF THE (DIIMINE)COPPER-CATALYZED ASYMMETRIC AZIRIDINATION OF ALKENES - NITRENE TRANSFER VIA LIGAND-ACCELERATED CATALYSIS [J].

LI, Z ;

QUAN, RW ;

JACOBSEN, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (21) :5889-5890

[44] ASYMMETRIC ALKENE AZIRIDINATION WITH READILY AVAILABLE CHIRAL DIIMINE-BASED CATALYSTS [J].

LI, Z ;

CONSER, KR ;

JACOBSEN, EN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) :5326-5327

[45] Catalytic allylic alkylation via the cross-dehydrogenative-coupling reaction between allylic sp3 C-H and methylenic sp3 C-H bonds [J].

Li, ZP ;

Li, CJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (01) :56-57

[46] Rhodium(II,II) dimer as an efficient catalyst for aziridination of sulfonamides and amidation of steroids [J].

Liang, JL ;

Yuan, SX ;

Chan, PWH ;

Che, CM .

ORGANIC LETTERS, 2002, 4 (25) :4507-4510

[47] Amidation of silyl enol ethers and cholesteryl acetates with chiral ruthenium(II) Schiff-base catalysts: catalytic and enantioselective studies [J].

Liang, JL ;

Yu, XQ ;

Che, CM .

CHEMICAL COMMUNICATIONS, 2002, (02) :124-125

[48]

Liang JL, 2002, ANGEW CHEM INT EDIT, V41, P3465, DOI 10.1002/1521-3773(20020916)41:18<3465::AID-ANIE3465>3.0.CO

[49]

2-D

[50]

Liang JL, 2002, CHEM-EUR J, V8, P1563, DOI 10.1002/1521-3765(20020402)8:7<1563::AID-CHEM1563>3.0.CO

← 1 2 3 4 5 6 7 →