Three-dimensional framework containing Mn(salen)+ and Re6Se8(CN)64- cluster

被引：63

作者：

Kim, Y ^{[1
]}

Park, SM ^{[1
]}

Kim, SJ ^{[1
]}

机构：

[1] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 08期

关键词：

cluster compounds; rhenium complexes; cyanide complexes; three-dimensional framework;

D O I：

10.1016/S1387-7003(02)00484-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three-dimensional framework material containing Mn(salen)(+) units and cyano-Re6Se8 clusters was prepared, and its crystal structure was determined by X-ray crystallography. The compound crystallized in the rhombohedral space group R (3) over barc with a = 16.1760(4) Angstrom, c = 44.965(1) Angstrom, = 10189.3(4) Angstrom(3), and Z = 6. In the structure, each anionic cluster, Re6Se8(CN)(6)(4-) was bridged by six Mn(salen)(+) units to form a three-dimensional framework. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：592 / 595

页数：4

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