Synthesis and characterization of poly(vinylpyrrolidone-co-vinylphosphonic acid) copolymers

被引：37

作者：

Erdemi, H ^{[1
]}

Bozkurt, A ^{[1
]}

机构：

[1] Fatih Univ, Dept Chem, TR-34500 Istanbul, Turkey

来源：

EUROPEAN POLYMER JOURNAL | 2004年 / 40卷 / 08期

关键词：

poly(vinylpyrrolidone); poly(vinylphosphonic acid); copolymer; thermal properties; proton conductivity;

D O I：

10.1016/j.eurpolymj.2004.04.001

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Radical copolymerizations of 1-vinyl-2-pyrrolidone (VP) with vinylphosphonic acid (VPA) at different feed ratios were investigated. The copolymers were characterized by H-1-NMR, C-13-NMR and FT-IR. The copolymer composition was determined from the elemental analysis. Thermogravimetric analysis (TG) illustrates that the copolymers are stable up to 200 C. Temperature dependence of the alternating current (AC) conductivities were investigated by means of impedance spectroscopy. The direct current (DC) conductivities of the samples are derived from the AC conductivity data. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：1925 / 1929

页数：5

共 9 条

[1] Allcock H. R., 1990, CONT POLYM CHEM, P196
[2] Proton conducting copolymers on the basis of vinylphosphonic acid and 4-vinylimidazole
Bozkurt, A
Meyer, WH
Gutmann, J
Wegner, G
[J]. SOLID STATE IONICS, 2003, 164 (3-4) : 169 - 176
[3] Synthesis and characterization of proton-conducting copolymers on the basis of vinylpyrrolidone and acrylamido sulfonic acid
Bozkurt, A
Ekinci, Ö
Meyer, WH
[J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 90 (12) : 3347 - 3353
[4] Proton-conducting poly(vinylpyrrolidon)-polyphosphoric acid blends
Bozkurt, A
Meyer, WH
[J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2001, 39 (17) : 1987 - 1994
[5] Proton-conducting polymer electrolytes based on phosphoric acid
Bozkurt, A
Ise, M
Kreuer, KD
Meyer, WH
Wegner, G
[J]. SOLID STATE IONICS, 1999, 125 (1-4) : 225 - 233
[6] Recent developments in high-temperature proton conducting polymer electrolyte membranes
Jannasch, P
[J]. CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2003, 8 (01) : 96 - 102
[7] TGA/FTIR studies on the thermal degradation of some polymeric sulfonic and phosphonic acids and their sodium salts
Jiang, DD
Yao, Q
McKinney, MA
Wilkie, CA
[J]. POLYMER DEGRADATION AND STABILITY, 1999, 63 (03) : 423 - 434
[8] Proton conducting polymer blends and hybrid organic inorganic materials
Lassègues, JC
Grondin, J
Hernandez, M
Marée, B
[J]. SOLID STATE IONICS, 2001, 145 (1-4) : 37 - 45
[9] Anhydrous proton-conducting polymers
Schuster, ME
Meyer, WH
[J]. ANNUAL REVIEW OF MATERIALS RESEARCH, 2003, 33 : 233 - 261

← 1 →