Characterization of a thin CeO2-ZrO2-Y2O3 films electrochemical deposited on stainless steel

被引:26
作者
Avramova, I.
Stoychev, D.
Marinova, Ts.
机构
[1] Bulgarian Acad Sci, Inst Gen & Inorgan Chem, BU-1113 Sofia, Bulgaria
[2] Bulgarian Acad Sci, Inst Phys Chem, BU-1113 Sofia, Bulgaria
关键词
CeO2-ZrO2-Y2O3; oxide; electrodeposition; XPS;
D O I
10.1016/j.apsusc.2006.02.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, we report for the first time formation of a thin CeO2-ZrO2-Y2O3 films electrodeposited on a stainless steel substrate. The samples have been characterized by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and X-ray diffraction (XRD). The XRD and XPS data indicate formation of a solid solution and additional existence of Cc(3+) states near the surface. After annealing, SEM examination has shown a microstructure formed by dispersed spherical agglomerates having a size between 20 and 60 nm. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:1365 / 1370
页数:6
相关论文
共 29 条
[21]   Oxygen ion diffusivity, surface exchange and ionic conductivity in single crystal Gadolinia doped Ceria [J].
Ruiz-Trejo, E ;
Sirman, JD ;
Baikov, YM ;
Kilner, JA .
SOLID STATE IONICS, 1998, 113 :565-569
[22]   Ordered ultra-thin cerium oxide overlayers on Pt(111) single crystal surfaces studied by LEED and XPS [J].
Schierbaum, KD .
SURFACE SCIENCE, 1998, 399 (01) :29-38
[23]   HARTREE-SLATER SUBSHELL PHOTOIONIZATION CROSS-SECTIONS AT 1254 AND 1487EV [J].
SCOFIELD, JH .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1976, 8 (02) :129-137
[24]   Electrochemical deposition of thin zirconia films on stainless steel 316 L [J].
Stefanov, P ;
Stoychev, D ;
Valov, I ;
Kakanakova-Georgieva, A ;
Marinova, T .
MATERIALS CHEMISTRY AND PHYSICS, 2000, 65 (02) :222-225
[25]  
Stefanov P., 2002, P 6 INT C FUND APPL, V1, P198
[26]   Ionic conduction in nanocrystalline materials [J].
Tuller, HL .
SOLID STATE IONICS, 2000, 131 (1-2) :143-157
[27]  
West Anthony R., 1999, BASIC SOLID STATE CH, Vsecond, P1
[28]   RAMAN-SCATTERING STUDY OF CUBIC-TETRAGONAL PHASE-TRANSITION IN ZR1-XCEXO2 SOLID-SOLUTION [J].
YASHIMA, M ;
ARASHI, H ;
KAKIHANA, M ;
YOSHIMURA, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (04) :1067-1071
[29]   A review on the status of anode materials for solid oxide fuel cells [J].
Zhu, WZ ;
Deevi, SC .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2003, 362 (1-2) :228-239