Synthesis and structure of a five-coordinate organochromium(III) thiolate complex from a chromium(II) alkyl precursor

被引：28

作者：

Fryzuk, MD

Leznoff, DB

Rettig, SJ

机构：

[1] Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 23期

关键词：

D O I：

10.1021/om970574l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the Cr(II) methyl complex, CrMe[N(SiMe2CH2PPh2)(2)], with diphenyl disulfide (PhSSPh) leads to the formation of the five-coordinate, paramagnetic complex CrMe(SPh)[N(SiMe2CH2PPh2)(2)] by an overall one-electron oxidation. The complex is unusual in that the phenyl thiolate moiety is terminal and does not engage in bridging to generate a dinuclear system having octahedral Cr(III) centers. The complex was characterized both in solution and in the solid state.

引用

页码：5116 / 5119

页数：4

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