An unambiguous electron-counting notation for metallaboratranes

被引：156

作者：

Hill, Anthony F. ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Inst Adv Studies, Canberra, ACT, Australia

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 20期

关键词：

D O I：

10.1021/om0602512

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A cohesive notation for indicating the overall number of electrons associated with metallaboratanes and metal-boron (M-B) dative unit that eliminated confusion arising from electron-counting formalisms was investigated. Metallaboratanes are a new class of compound in which a metal-boron dative is housed within a cage or chelated structure and the majority of such complexes were developed from investigations of the chemistry of poly(methimazolyl) borates. It is anticipated that as the field of metallaboratanes develops, a spectrum of behavior for the M-B bond will emerge, involving different degrees of electron transfer from the metal to the Lewis acid. The results of computational studies of the two metallaboratanes are distinct to provide a gradation of M-B dative interactions. It is expected that more subtleties will emerge from computational studies of metallaboratanes, with several factors contributing to the Lewis basicity of a transition metal.

引用

页码：4741 / 4743

页数：3

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