Air- and moisture-stable secondary phosphine oxides as preligands in catalysis

被引:194
作者
Ackermann, Lutz [1 ]
机构
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
来源
SYNTHESIS-STUTTGART | 2006年 / 10卷 / 10期
关键词
asymmetric catalysis; cross-coupling; nucleophilic additions; phosphorus; transition metals;
D O I
10.1055/s-2006-926427
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The application of secondary phosphine oxides to catalysis is reviewed. A survey of the literature up to summer 2005 is provided, covering the use of these air- and moisture-stable preligands in transformations catalyzed by transition-metal complexes and their use as precatalysts in nucleophilic catalysis. 1 Introduction 2 Syntheses of Phosphine Oxides and Their Metal Complexes Relevant to Catalysis 3 Transition-Metal-Catalyzed Reactions 3.1 Carbon-Substituted Secondary Phosphine Oxides 3.2 Heteroatom-Substituted Secondary Phosphine Oxides 3.3 Asymmetric Transition-Metal-Catalyzed Reactions 4 Nucleophilic Catalysis 5 Summary and Outlook.
引用
收藏
页码:1557 / 1571
页数:15
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