α-Polonium coordination networks constructed from bis(imidazole) ligands

被引：79

作者：

Abrahams, BF ^{[1
]}

Hoskins, BF ^{[1
]}

Robson, R ^{[1
]}

Slizys, DA ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

CRYSTENGCOMM | 2002年 / 4卷

关键词：

D O I：

10.1039/b204849c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two types of bis(imidazole) ligands-1,4-bis(imidazol-1-ylmethyl) benzene (bix) and 1,4-bis( imidazolyl)-2-butyne (bib) - have been used to bridge octahedral metal centres and form simple cubic networks. Crystal structures of Cd(bix)(3) (ClO4)(2), Cd( bix)(3) (NO3)(2), Zn(bib)(3) (BF4)(2) and Co(bib)(3) (NO3)(2) reveal that all possess the alpha-polonium topology and are triply interpenetrating.

引用

页码：478 / 482

页数：5

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