Synthesis and self-assembly of giant porphyrin discs

被引：49

作者：

Lensen, MC

van Dingenen, SJT

Elemans, JAAW

Dijkstra, HP

van Klink, GPM

van Koten, G

Gerritsen, JW

Speller, S

Nolte, RJM

Rowan, AE

机构：

[1] Univ Nijmegen, NSRIM Ctr, NL-6525 ED Nijmegen, Netherlands

[2] Univ Utrecht, Dept Met Mediated Synth, Debye Inst, NL-3508 TC Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 07期

关键词：

D O I：

10.1039/b401324g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A giant porphyrin disc (M-w = 15 kDa) has been synthesized and its self-assembly behaviour at an interface studied by liquid STM which reveals the presence of huge domains (> 400 X 400 nm(2)) of very well ordered and molecularly resolved columnar stacks.

引用

收藏

页码：762 / 763

页数：2

相关论文

共 14 条

[1] A self-assembled light-harvesting array of seven porphyrins in a wheel and spoke architecture [J].

Ambroise, A ;

Li, JZ ;

Yu, LH ;

Lindsey, JS .

ORGANIC LETTERS, 2000, 2 (17) :2563-2566

[2] Molecular acrobatics: Self-assembly of calixarene-porphyrin cages [J].

Baldini, L ;

Ballester, P ;

Casnati, A ;

Gomila, RM ;

Hunter, CA ;

Sansone, F ;

Ungaro, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (46) :14181-14189

[3] Dendrimers as scaffolds for the synthesis of spherical porphyrin arrays [J].

Ballester, P ;

Gomila, RM ;

Hunter, CA ;

King, ASH ;

Twyman, LJ .

CHEMICAL COMMUNICATIONS, 2003, (01) :38-39

[4] Hexakis porphyrinato benzenes. A new class of porphyrin arrays [J].

Biemans, HAM ;

Rowan, AE ;

Verhoeven, A ;

Vanoppen, P ;

Latterini, L ;

Foekema, J ;

Schenning, APHJ ;

Meijer, EW ;

de Schryver, FC ;

Nolte, RJM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (43) :11054-11060

[5]

Choi MS, 2002, CHEM-EUR J, V8, P2668

[6] Shape-persistent nanosize organometallic complexes:: Synthesis and application in a nanofiltration membrane reactor [J].

Dijkstra, HP ;

Kruithof, CA ;

Ronde, N ;

van de Coevering, R ;

Ramón, DJ ;

Vogt, D ;

van Klink, GPM ;

van Koten, G .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (03) :675-685

[7] Self-organization of self-assembled photonic materials into functional devices: Photo-switched conductors [J].

Drain, CM .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :5178-5182

[8] Scanning probe studies of porphyrin assemblies and their supramolecular manipulation at a solid-liquid interface [J].

Elemans, JAAW ;

Lensen, MC ;

Gerritsen, JW ;

van Kempen, H ;

Speller, S ;

Nolte, RJM ;

Rowan, AE .

ADVANCED MATERIALS, 2003, 15 (24) :2070-+

[9] Self-assembly of oligomeric porphyrin rings [J].

Haycock, RA ;

Hunter, CA ;

James, DA ;

Michelsen, U ;

Sutton, LR .

ORGANIC LETTERS, 2000, 2 (16) :2435-2438

[10] Aided self-assembly of porphyrin nanoaggregates into ring-shaped architectures [J].

Lensen, MC ;

Takazawa, K ;

Elemans, JAAW ;

Jeukens, CRLPN ;

Christianen, PCM ;

Maan, JC ;

Rowan, AE ;

Nolte, RIM .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (04) :831-839