Ammonia gas sensor based on electrosynthesized polypyrrole films

被引:141
作者
Carquigny, Stephanie [1 ,2 ]
Sanchez, Jean-Baptiste [2 ]
Berger, Franck [2 ]
Lakard, Boris [1 ]
Lallemand, Fabrice [1 ]
机构
[1] Univ Franche Comte, CNRS, Inst UTINAM, UMR 6213, F-25030 Besancon, France
[2] Univ Franche Comte, LCPR AC, UMR CEA E4, F-25030 Besancon, France
关键词
Gas sensor; Ammonia; Polypyrrole; Electrochemistry; POLYANILINE THIN-FILMS; CONDUCTING POLYMERS; CONJUGATED POLYMERS; SENSING BEHAVIORS; NH3; GAS; FABRICATION; POLY(PYRROLE); TRANSISTORS; SENSITIVITY; PERFORMANCE;
D O I
10.1016/j.talanta.2008.10.056
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, design and fabrication of micro-gas-sensors, polymerization and deposition of poly(pyrrole) thin films as sensitive layer for the micro-gas-sensors by electrochemical processing, and characterization of the polymer films by FTIR, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), are reported. The change in conductance of thin polymer layers is used as a sensor signal. The behaviours, including sensitivity, reproducibility and reversibility, to various ammonia gas concentrations ranging from 8 ppm to 1000 ppm are investigated. The influence of the temperature on the electrical response of the sensors is also studied. The experimental results show that these ammonia gas sensors are efficient since they are sensitive to ammonia, reversible and reproducible at room temperature. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:199 / 206
页数:8
相关论文
共 68 条
[1]   POLYANILINE THIN-FILMS FOR GAS-SENSING [J].
AGBOR, NE ;
PETTY, MC ;
MONKMAN, AP .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 28 (03) :173-179
[2]   A simple method to estimate the oxidation state of polyanilines [J].
Albuquerque, JE ;
Mattoso, LHC ;
Balogh, DT ;
Faria, RM ;
Masters, JG ;
MacDiarmid, AG .
SYNTHETIC METALS, 2000, 113 (1-2) :19-22
[3]   The first truly all-polymer electrochromic devices [J].
Argun, AA ;
Cirpan, A ;
Reynolds, JR .
ADVANCED MATERIALS, 2003, 15 (16) :1338-+
[4]   Electrosynthesis of polypyrrole/sulfonated polyaniline composite films and their applications for ammonia gas sensing [J].
Bai, Hua ;
Chen, Qi ;
Li, Chun ;
Lu, Chanhui ;
Shi, Gaoquan .
POLYMER, 2007, 48 (14) :4015-4020
[5]   Gas sensors based on conducting polymers [J].
Bai, Hua ;
Shi, Gaoquan .
SENSORS, 2007, 7 (03) :267-307
[6]   Conducting polymer sensors for monitoring aromatic hydrocarbons using an electronic nose [J].
Barisci, JN ;
Wallace, GG ;
Andrews, MK ;
Partridge, AC ;
Harris, PD .
SENSORS AND ACTUATORS B-CHEMICAL, 2002, 84 (2-3) :252-257
[7]   The development and characterisation of conducting polymeric-based sensing devices. [J].
Brady, S ;
Lau, KT ;
Megill, W ;
Wallace, GG ;
Diamond, D .
SYNTHETIC METALS, 2005, 154 (1-3) :25-28
[8]   The effect of initial conductivity and doping anions on gas sensitivity of conducting polypyrrole films to NH3 [J].
Brie, M ;
Turcu, R ;
Neamtu, C ;
Pruneanu, S .
SENSORS AND ACTUATORS B-CHEMICAL, 1996, 37 (03) :119-122
[9]   A glucose-sensing polymer [J].
Chen, GH ;
Guan, ZB ;
Chen, CT ;
Fu, LT ;
Sundaresan, V ;
Arnold, FH .
NATURE BIOTECHNOLOGY, 1997, 15 (04) :354-357
[10]   Sensing behaviors of polypyrrole sensor under humidity condition [J].
Cho, JH ;
Yu, JB ;
Kim, JS ;
Sohn, SO ;
Lee, DD ;
Huh, JS .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 108 (1-2) :389-392