TEAF mediated hydroxylation of allylic bromide: A facile synthesis of 4-methoxycarbonyl-2(5H)-furanone

被引：21

作者：

Beltaief, I

Besbes, R

Amri, H

Villieras, J

机构：

[1] FAC SCI TUNIS,CHIM ORGAN & ORGANOMET LAB,TUNIS 1060,TUNISIA

[2] FAC SCI & TECH,CNRS,ORGAN SYNTH LAB,F-44072 NANTES 03,FRANCE

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 05期

关键词：

D O I：

10.1016/S0040-4039(96)02437-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A simple two-step synthesis of 4-methoxycarbonyl-2(SH)-furanone consisting of formylation of dimethyl 2-(bromomethyl) fumarate, followed by acid catalysed transesterification in methanol was carried out. It led to the corresponding substituted furanone in 67% global yield. (C) 1997, Published by Elsevier Science Ltd.

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页码：813 / 814

页数：2

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