Lipase-catalyzed synthesis of geranyl methacrylate by transesterification: study of reaction parameters

被引：26

作者：

Athawale, V ^{[1
]}

Manjrekar, N ^{[1
]}

Athawale, M ^{[1
]}

机构：

[1] Univ Mumbai, Dept Chem, Bombay 400098, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 27期

关键词：

geraniol; lipase; methacrylate; controlled release perfume; oxime;

D O I：

10.1016/S0040-4039(02)00926-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The methacrylate ester or geraniol was synthesized using various lipases, such as porcine pancreatic lipase (PPL). Candida rugosu lipase (CRL) and Pseudomonas cepacia lipase (Arnano-PS) as catalysts. The effects of reaction parameters such as type and amount of lipase, solvent. temperature and acylating agent on the conversion of geraniol to geranyl methacrylate was studied. The monomer obtained Could be used in the synthesis of controlled release pet-fume. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4797 / 4800

页数：4

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