Synthesis, characterization and reactivities of Schiff-base complexes of ruthenium(III)

被引：23

作者：

Chatterjee, D ^{[1
]}

Mitra, A ^{[1
]}

机构：

[1] Cent Mech Engn Res Inst, Chem Sect, Durgapur 713209, India

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 57卷 / 03期

关键词：

ruthenium complex; Schiff-base ligands; t-BuOOH; oxo transfer catalysis;

D O I：

10.1080/00958970410001662435

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Schiff-base complexes of ruthenium (1-5) have been synthesized using Schiff-base ligands derived by condensation of either 1,2-phenylenediamine with aldehydes (salicyldehyde, 2-pyridinecarboxaldehyde) or acetylacetone with amines (2-aminophenol, 2-aminomethylpyridine). All complexes were characterized by analytical, spectroscopic, conductance, magnetic moment and electrochemical studies. At room temperature, complexes 1-5 catalyze the oxidation of both saturated and unsaturated hydrocarbons using tert-butylhydroperoxide (t-BuOOH). A mechanism involving formation of and transfer from a reactive high valency Ru(V)-oxo species as the catalytic intermediate is proposed for the processes.

引用

页码：175 / 182

页数：8

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