Photochemical intermolecular C-H and C-F insertion of rhodium into pentafluoroanisole to generate a metallacycle; Conversion to a cyclic carbene complex

被引：22

作者：

Ballhorn, M ^{[1
]}

Partridge, MG ^{[1
]}

Perutz, RN ^{[1
]}

Whittlesey, MK ^{[1
]}

机构：

[1] UNIV YORK,DEPT CHEM,YORK YO1 5DD,N YORKSHIRE,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Irradiation of [(eta(5)-C5H5)Rh(PMe(3))(C2H4)] in pentafluoroanisole generates the metallacycle [(eta(5)-C5H5)(PMe(3))RhCH(2)OC(6)F4]; reaction of this complex with 1 equiv, of Ph(3)C(+)PF6(-) at 220 K generates [(eta(5)-C5H5)(PMe(3))Rh=C(H)OC6F4]PF6.

引用

页码：961 / 962

页数：2

共 17 条

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